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MSDS for
Paraldehyde, 98%
**** MATERIAL SAFETY DATA SHEET ****
Paraldehyde, 98%
**** SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION ****
MSDS Name: Paraldehyde, 98%
Company :Zhaofeng Chemical Co., Ltd.
For information , call: 0086-513-2609168，Fax:0086-513-2747788
For emergencies , call: 0086-513-2609168
**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+-----------------+-------------------------------------------------+---------------+----------------+
| CAS# | Chemical Name | % | EINECS# |
|---------------------|------------------------------------------------|-----------------|------------------|
| 123-63-7 | Paraldehyde | 98% | 204-639-8 |
+------------------+------------------------------------------------+----------------+----------------+
Hazard Symbols: F
Risk Phrases: 11
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. May be harmful if absorbed through the
skin.
Ingestion:
May cause irritation of the digestive tract. May be harmful if
swallowed.
Inhalation:
May cause respiratory tract irritation. May be harmful if inhaled.
Chronic:
Not available.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Flush skin with plenty of soap and water for at
least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Get medical aid immediately. Do NOT induce vomiting. If conscious and
alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure to fresh air
immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Will burn if involved in a fire. Flammable liquid
and vapor.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam. Use agent most appropriate to extinguish
fire.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Use spark-proof tools and explosion proof equipment. Avoid breathing
dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a cool, dry place. Store in a tightly closed
container. Flammables-area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Personal Protective Equipment
Eyes:
Wear chemical goggles. Wear safety glasses and
chemical goggles if splashing is possible.
Skin:
Wear appropriate protective gloves and clothing to
prevent skin exposure. Wear appropriate protective
gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR §1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant a respirator's use. Wear a
NIOSH/MSHA or European Standard EN 149 approved
full-facepiece airline respirator in the positive
pressure mode with emergency escape provisions.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Clear liquid
Appearance: colourless - yellow
Odor: Not available.
pH: Not available.
Vapor Pressure: 10 hPa @ 20 deg C
Viscosity: 1.19 cP 20 deg C
Boiling Point: 124 deg C @ 760.00mm Hg
Freezing/Melting Point: 12 deg C
Autoignition Temperature: 235 deg C ( 455.00 deg F)
Flash Point: 27 deg C ( 80.60 deg F)
Explosion Limits, lower: 1.30 vol %
Explosion Limits, upper: 1.70 vol %
Decomposition Temperature:
Solubility in water: 125 g/l water (25°C)
Specific Gravity/Density: .9920g/cm3
Molecular Formula:
Molecular Weight: 132.16
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 123-63-7: YK0525000
LD50/LC50:
CAS# 123-63-7: Draize test, rabbit, eye: 5 mg Severe; Oral, mouse:
LD50 = 2750 mg/kg; Oral, rabbit: LD50 = 3304 mg/kg; Oral, rat: LD50 =
1530 mg/kg; Skin, rabbit: LD50 = 14100 uL/kg.
Carcinogenicity:
Paraldehyde -
Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: PARALDEHYDE
Hazard Class: 3
UN Number: 1264
Packing Group: III
IMO
Shipping Name: PARALDEHYDE
Hazard Class: 3
UN Number: 1264
Packing Group: III
RID/ADR
Shipping Name: PARALDEHYDE
Hazard Class: 3
UN Number: 1264
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: F
Risk Phrases:
R 11 Highly flammable.
Safety Phrases:
S 9 Keep container in a well-ventilated place.
S 16 Keep away from sources of ignition - No
smoking.
S 29 Do not empty into drains.
S 33 Take precautionary measures against static
discharges.
WGK (Water Danger/Protection)
CAS# 123-63-7: No information available.
United Kingdom Occupational Exposure Limits
Canada
CAS# 123-63-7 is listed on Canada's DSL List.
CAS# 123-63-7 is listed on Canada's Ingredient Disclosure List.
Exposure Limits
CAS# 123-63-7: Not available.
US FEDERAL
TSCA
CAS# 123-63-7 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 12/16/2003 Revision #0 Date: Original.
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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